MATERIAL TECHNOLOGY AND APPLIED CHEMISTRY

Academic Year 2022/2023 - Teacher: Antonino POLLICINO

Expected Learning Outcomes

Knowledge and understanding: Basic knowledge of materials of interest for civil engineering, correlating their application characteristics to composition, structure, production and processing technologies

Applied knowledge and understanding skills: Ability to apply what has been learned during the lectures in the exercises carried out during the course.

Autonomy of judgment: Students learn to objectively evaluate what they have learned during lessons and exercises.

Communication skills: Students acquire communication skills that are formed both during the lessons, thanks to a continuous verbal conversation with the teacher, and during the oral exam.

Learning skills: Learning skills are assessed through the oral exam and exercises which are an important part of the course.

Course Structure

The course will be done through lectures, ongoing tests and exercises. If course should be carried out in mixed mode or remotely, it may be necessary to introduce changes with respect to previous statements, in line with the programme planned and outlined in the syllabus.

Required Prerequisites

Basic knowledge on the nature of chemical bonds, on the structure of crystalline and amorphous solids, on the thermodynamics of state transitions and on electrochemical processes acquired with the Chemistry course

Detailed Course Content

1.GENERAL INTRODUCTION TO MATERIALS. The Price and Availability of Materials. 2. STRUCTURE AND PROPERTIES. MECHANICAL PROPERTIES. The Elastic Moduli. Definition of Stress. Definition of Strain. Hooke's Law. Measurement of Young's Modulus. Bonding between Atoms. The condensed states of matter. Interatomic forces. Packing of Atoms in Solids. The Physical Basis of Young's Modulus. Moduli of Crystals. Rubbers and the Glass Transition Temperature. Composites. Yield Strength, Tensile Strength, and Ductility. Linear and Nonlinear Elasticity. Load–Extension Curves for Nonelastic (Plastic) Behavior. True Stress–Strain Curves for Plastic Flow. Plastic Work. Tensile Testing. The Hardness Test. Dislocations and Yielding in Crystals. Strengthening Methods and Plasticity of Polycrystals  Fast Fracture and Toughness. Micromechanisms of Fast Fracture. Probabilistic Fracture of Brittle Materials. Fatigue Failure. Creep and Creep Fracture. Kinetic Theory of Diffusion. Mechanisms of Creep, and Creep-Resistant Materials. 3. METALS Metal Structures. Phase Diagrams. Driving Force for Solidification. Solid-State Phase Diffusive Transformations. Solid-State Phase Changes. Nucleation. Displacive Transformations. Diffusive F.C.C. to B.C.C. Transformation in Pure Iron. Time–Temperature–Transformation Diagram. Displacive F.C.C. to B.C.C. Transformation. Details of Martensite Formation. Light Alloys. Solid Solution Hardening. Age (Precipitation) Hardening. Carbon Steels. Microstructures after slow cooling and their mechanical properties. Quenched-and-Tempered Steels. Alloy Steels. Stainless Steels. Cast Iron. 4.POLYMERS AND COMPOSITES. Polymer Structures. Molecular Length. Molecular Architecture. Molecular Packing and Glass Transition. Mechanical Properties of Polymers. Stiffness—Time and Temperature Dependent Modulus. Strength—Cold Drawing and Crazing. Composites. Properties of Composites. Fiber Composites. Modulus. Tensile Strength. Toughness. 5. CORROSION. Oxidation of Materials.  The Energy of Oxidation. Rates of Oxidation. Micromechanisms. Wet Corrosion of Materials. Voltage Differences as the Driving Force for Wet Oxidation. Pourbaix (Electrochemical Equilibrium) Diagrams. Localized Attack. 6. CEMENT AND CONCRETE Chemistry of Cement. Structure of Portland Cement. Concrete. Strength of Cement and Concrete. High-Strength Cement. Reinforcing Cement and Concrete. Durability.

Textbook Information

1. W. D. Callister, Jr.: “Materials Science and Engineering; An Introduction” - Wiley

2. W. F. Smith: “Materials Science and Engineering” - McGraw - Hill

3 . D. R. Askeland, P. P. FulayW. J. Wright, "The Science and Engineering of materials" – Cengage learning   

4. L. Bertolini, Materiali da costruzione – Città Studi Ed. Vol. 1 e 2

5. G.Bianchi, F. Mazza, Corrosione e protezione dei metalli – Collana tecnica AIM

6. 5. Class notes

Course Planning

 SubjectsText References
1PROPRIETÀ MECCANICHEDiapositive Lezioni 1-9. Commenti alle diapositive Lezioni 1-9 (pp 1-45)
2METALLIDiapositive Lezioni 10-16. Commenti alle diapositive Lezioni 10-16 (pp 46-97)
3POLIMERI E COMPOSITIDiapositive Lezioni 17-19. Commenti alle diapositive Lezioni 17-19 (pp. 98-119)
4CORROSIONEDiapositive Lezioni 20-24. Commenti alle diapositive Lezioni 20-24 (pp 120-147)
5LEGANTIDiapositive Lezioni 25 -32. Commenti alle diapositive Lezioni 25-32 (pp 148-197)

Learning Assessment

Learning Assessment Procedures

During the lesson period, learning will be verified through three in itinere tests (two written and one oral). The first (October 24, 2022) will concern the mechanical properties of materials; the second (23 November 2022) will focus on topics related to metals, polymers and composites. The third (22-23 December 2022), in oral form, will concern the exposition of topics related to corrosion and binders. Passing the first test will allow you to go to the second and so on. The final exam (oral), to be passed within one calendar year from the date of passing the first test, will focus only on the topics not covered in the ongoing tests

During the year, seven (ordinary) exam sessions are scheduled plus four sessions reserved for out-of-course students.

During the periods allowed by the academic calendar it is also possible, by contacting the teacher by e-mail or by telephone, to arrange further exam interviews (on a weekly basis)

The final exam (oral) will focus on the whole program for those who have not passed any ongoing tests or on the portions of the program not acquired with the ongoing tests. When you contact the teacher to agree on the date of the interview, you can communicate your desire to divide the final exam into several interviews and agree on the contents. In any case, the final exam must be passed within one calendar year of passing the first interview.

How to register for an exam session: Booking on the university portal

The exam consists in the oral presentation of topics addressed during the course

The evaluation of the exam is based on the following criteria: level of knowledge of the required topics, expressive ability and language properties, ability to apply knowledge to simple case studies, ability to connect the different themes of the teaching program.

Verification of learning can also be carried out electronically, should the conditions require it.